Direct Observation of Ultrafast Exciton Formation in a Monolayer of WSe2

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

  • Philipp Steinleitner - , Universität Regensburg (Autor:in)
  • Philipp Merkl - , Universität Regensburg (Autor:in)
  • Philipp Nagler - , Universität Regensburg (Autor:in)
  • Joshua Mornhinweg - , Universität Regensburg (Autor:in)
  • Christian Schüller - , Universität Regensburg (Autor:in)
  • Tobias Korn - , Universität Regensburg (Autor:in)
  • Alexey Chernikov - , Universität Regensburg (Autor:in)
  • Rupert Huber - , Universität Regensburg (Autor:in)

Abstract

Many of the fundamental optical and electronic properties of atomically thin transition metal dichalcogenides are dominated by strong Coulomb interactions between electrons and holes, forming tightly bound atom-like states called excitons. Here, we directly trace the ultrafast formation of excitons by monitoring the absolute densities of bound and unbound electron-hole pairs in single monolayers of WSe2 on a diamond substrate following femtosecond nonresonant optical excitation. To this end, phase-locked mid-infrared probe pulses and field-sensitive electro-optic sampling are used to map out the full complex-valued optical conductivity of the nonequilibrium system and to discern the hallmark low-energy responses of bound and unbound pairs. While the spectral shape of the infrared response immediately after above-bandgap injection is dominated by free charge carriers, up to 60% of the electron-hole pairs are bound into excitons already on a subpicosecond time scale, evidencing extremely fast and efficient exciton formation. During the subsequent recombination phase, we still find a large density of free carriers in addition to excitons, indicating a nonequilibrium state of the photoexcited electron-hole system.

Details

OriginalspracheEnglisch
Seiten (von - bis)1455-1460
Seitenumfang6
FachzeitschriftNano letters
Jahrgang17
Ausgabenummer3
PublikationsstatusVeröffentlicht - 8 März 2017
Peer-Review-StatusJa
Extern publiziertJa

Externe IDs

PubMed 28182430

Schlagworte

Schlagwörter

  • atomically thin 2D crystals, Dichalcogenides, exciton formation, ultrafast dynamics