Diffusion study by IR micro-imaging of molecular uptake and release on mesoporous zeolites of structure type CHA and LTA

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

  • Mauricio Rincon Bonilla - , Universität Leipzig, University of Queensland (Autor:in)
  • Tobias Titze - , Universität Leipzig (Autor:in)
  • Franz Schmidt - , Technische Universität Dresden (Autor:in)
  • Dirk Mehlhorn - , Universität Leipzig (Autor:in)
  • Christian Chmelik - , Universität Leipzig (Autor:in)
  • Rustem Valiullin - , Universität Leipzig (Autor:in)
  • Suresh K. Bhatia - , University of Queensland (Autor:in)
  • Stefan Kaskel - , Professur für Anorganische Chemie (I) (AC1) (Autor:in)
  • Ryong Ryoo - , Institute for Basic Science, Korea Advanced Institute of Science & Technology (KAIST) (Autor:in)
  • Jörg Kärger - , Universität Leipzig (Autor:in)

Abstract

The presence of mesopores in the interior of microporous particles may significantly improve their transport properties. Complementing previous macroscopic transient sorption experiments and pulsèd field gradient NMR self-diffusion studies with such materials, the present study is dedicated to an in-depth study of molecular uptake and release on the individual particles of mesoporous zeolitic specimens, notably with samples of the narrow-pore structure types, CHA and LTA. The investigations are focused on determining the time constants and functional dependences of uptake and release. They include a systematic variation of the architecture of the mesopores and of the guest molecules under study as well as a comparison of transient uptake with blocked and un-blocked mesopores. In addition to accelerating intracrystalline mass transfer, transport enhancement by mesopores is found to be, possibly, also caused by a reduction of transport resistances on the particle surfaces.

Details

OriginalspracheEnglisch
Seiten (von - bis)2662-2688
Seitenumfang27
FachzeitschriftMaterials
Jahrgang6
Ausgabenummer7
PublikationsstatusVeröffentlicht - 2013
Peer-Review-StatusJa

Schlagworte

ASJC Scopus Sachgebiete

Schlagwörter

  • Diffusion, IR Micro-Imaging, Mesoporous zeolites, NaCaA, Olefins, Paraffins, SAPO-34, Surface barriers

Bibliotheksschlagworte