Cumulant approach and coupled-cluster method for many-particle systems
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
Abstract
Cumulants represent a natural language for expressing macroscopic properties of many-body systems. The most important property of cumulants is that of size consistency, i.e. a cumulant expression for an extensive variable scales with the size of the system, independent of possible further approximations used in the evaluation procedure. Cumulants can be considered as a generalization of linked diagrams known from diagrammatic technique of many-body theory. In this paper we outline a recently introduced method based on cumulants in order to derive expressions for zero-temperature properties of many-particle systems, i.e. the ground-state energy, static expectation values and dynamical correlation functions. This cumulant formalism allows one to describe weakly and strongly correlated systems along the same lines. We show that the coupled-cluster method known from quantum chemistry can be derived from our cumulant approach. Finally, we demonstrate the usefulness of the cumulant method by applying it to examples from solid-state physics and quantum chemistry.
Details
Originalsprache | Englisch |
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Seiten (von - bis) | 217-223 |
Seitenumfang | 7 |
Fachzeitschrift | Molecular physics : MP ; an international journal in the field of chemical physics |
Jahrgang | 94 |
Ausgabenummer | 1 |
Publikationsstatus | Veröffentlicht - 1 Mai 1998 |
Peer-Review-Status | Ja |