The bond behaviour of concrete specimens with carbon textile reinforcement was investigated in the presented research programme. Pull-out specimens were cast from self-compacting concrete with expansive admixtures and in this way chemical prestress was introduced. The aim of the research was to compare bond behaviour between prestressed specimens and non-prestressed control specimens. During pull-out tests, the pull-out force and notch opening were measured with a load cell and laser sensors. Further, bond - slip and pull-out force - crack width relationships were drawn and compared for prestressed and non-prestressed specimens. Chemically prestressed specimens reached 24% higher bond strength than non-prestressed ones. It can be therefore concluded, that chemical prestressing positively influences the bond behaviour of concrete with textile reinforcement and thus better utilisation of its properties can be provided.