Since conversion and intercalation reactions during battery charging and discharging may cause substantial volume changes and irreversible structural transformations that severely affect cathode performance, copper metal has been shown to be a reliable substitute for conventional Li-ion hosting cathodes. However, similar to the shuttle effect in Li-S batteries, the main obstacle coupling Li and Cu is the deposition of reduced Cu²⁺ on the surface of Li during charging. In this study, the diffusion of Cu ions towards the Li foil was suppressed by employing a carbon-coated separator. Moreover, the high-rate capacity of 596 mAh g_Cu⁻¹ at a current density of 837 mA g_Cu⁻¹ was achieved by employing 100 nm thick Cu-film fabricated by atomic layer deposition (ALD), owing to its high surface area, which facilitated rapid redox reactions. With metallic Sb anode, a Cu-Sb full cell exhibits a reversible discharge capacity of 117 mAh g_Cu⁻¹ (12.3 µAh cm⁻²) at a relativity high current density of 837 mA g_Cu⁻¹. Constructing Cu thin films via ALD might open up new opportunities for replacing traditional Li ion-hosting cathodes in Li-ion microbatteries.