Advancements in rare earth metal-organic frameworks: Harnessing the power of photonics and beyond

Publikation: Beitrag in Fachzeitschrift › Übersichtsartikel (Review) › Beigetragen › Begutachtung

Beitragende

  • Yahui Zhang - , University of Science and Technology of China (USTC) (Autor:in)
  • Penghui Wei - , University of Science and Technology of China (USTC) (Autor:in)
  • Ziwen Li - , University of Science and Technology of China (USTC) (Autor:in)
  • Yuzhi Sun - , University of Science and Technology of China (USTC) (Autor:in)
  • Yannan Liu - , Center for Advancing Electronics Dresden (cfaed), Professur für Molekulare Funktionsmaterialien (cfaed), Shanghai Jiao Tong University (Autor:in)
  • Shengyun Huang - , University of Science and Technology of China (USTC), CAS - Chinese Academy of Sciences (Autor:in)

Abstract

Metal-organic frameworks (MOFs) represent an emerging category of porous crystalline materials, notable for their high porosity, adjustable pore sizes and elevated Lewis acid contents. Rare earth MOFs (RE-MOFs), a specific subset of MOFs, use rare earth ions or clusters as central metal linkers, rendering advantages of both MOFs and rare earth ions. The distinctive feature of rare earth ions with unfilled 4f electron shells endows them with elevated coordination numbers and unique photophysical characteristics. Besides, the diversity of ligands within MOF frameworks effectively channels the antenna effect to sensitize the rare earth ions, resulting in enhanced photon emission, making RE-MOFs a kind of promising material in the photonics field, including photocatalysis, fluorescent probes, light-emitting, temperature sensing, near infrared (NIR) emission and more. This review presents the recent progress of photonic RE-MOFs creatively categorized by rare earth elements to demonstrate their great potential in photonics. The inherent correlation between structure of RE-MOFs and their photonic properties are systematically and comprehensively discusssed. Moreover, we highlight several key development directions of advanced photonic RE-MOFs to guide the further design.

Details

OriginalspracheEnglisch
Aufsatznummer215905
FachzeitschriftCoordination chemistry reviews
Jahrgang514
PublikationsstatusVeröffentlicht - 1 Sept. 2024
Peer-Review-StatusJa

Schlagworte

ASJC Scopus Sachgebiete

  • Allgemeine Chemie - Fluorescence probes, Near-infrared luminescence, Photocatalysis, Photonic, Rare-earth metal–organic frameworks
  • Physikalische und Theoretische Chemie - Fluorescence probes, Near-infrared luminescence, Photocatalysis, Photonic, Rare-earth metal–organic frameworks
  • Anorganische Chemie - Fluorescence probes, Near-infrared luminescence, Photocatalysis, Photonic, Rare-earth metal–organic frameworks
  • Werkstoffchemie - Fluorescence probes, Near-infrared luminescence, Photocatalysis, Photonic, Rare-earth metal–organic frameworks

Schlagwörter

  • Fluorescence probes, Near-infrared luminescence, Photocatalysis, Photonic, Rare-earth metal–organic frameworks