Advanced Redox Electrochemical Capacitor Diode (CAPode) Based on Parkerite (Ni3Bi2S2) with High Rectification Ratio for Iontronic Applications
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
Abstract
Recently, electrochemical capacitor diodes (CAPodes) have been introduced as a new type of capacitive diode analogues. This device realizes unidirectional charging of ultracapacitors based on ion sieving mechanisms. Here, a new redox CAPode system is presented in which hydroxide ions react with nickel bismuth sulfide on nickel foam as a battery-like electrode. This redox reaction leads to a high capacitance in a specific polarization window. However, for reversed bias this Faradaic electrode becomes inactive as it does not react with potassium cations, resulting in efficient blocking. By adapting counter electrode materials, mass loading, utilized substrates, and electrolyte concentrations a very high rectification ratio (RI = 37 and RII = 0.96 at 10 mV s−1) is achieved, significantly surpassing the performance of other reported redox-type CAPodes. Moreover, this system shows an outstanding long-term stability of a rectification retention of 90% for RII over 5000 repolarization cycles. Additionally, operando electrochemical measurements provide deep insights into the charge/discharge mechanism leading to a rationalization of the proposed concept. The integrated device, tested in logic gate circuits such as AND and OR gates, shows prospective results in ionologic applications.
Details
Originalsprache | Englisch |
---|---|
Aufsatznummer | 2405640 |
Fachzeitschrift | Advanced functional materials |
Jahrgang | 34 |
Ausgabenummer | 45 |
Publikationsstatus | Veröffentlicht - 2024 |
Peer-Review-Status | Ja |
Externe IDs
Mendeley | 55140df8-d7fe-336f-881c-fb758b40b373 |
---|
Schlagworte
ASJC Scopus Sachgebiete
Schlagwörter
- electrochemical capacitor-diodes (CAPodes), hybrid electrochemical capacitors, ionic diodes, logic gates, nickel bismuth sulfide (NiBiS), nickel bismuth sulfide (Ni3Bi2S2)