Lithium metal is a promising negative electrode material for solid-state batteries (SSBs). However, uncontrolled lithium deposition and stripping cause several issues during cycling. Herein, the microporous carbon YP-50F and its modifications obtained by thermal ethene-based chemical vapor deposition (CVD) are investigated as 3D host to accommodate and control the deposition of metallic lithium. In half-cells vs. lithium, the CVD-YP composite electrode with Li₆PS₅Cl electrolyte shows significantly higher initial coulombic efficiency (79.5 %) than the pristine carbon (55.3 %) due to the reduction of side reactions. The metallic character of the deposited lithium is evidenced by ⁷Li Nuclear Magnetic Resonance spectroscopy. However, full cells with nickel-rich NCM (LiNi_0.9Co_0.05Mn_0.05O₂) positive electrode and CVD-YP composite negative electrode show reasonable performance over 50 cycles without occurrence of (micro-) short-circuits (in contrast to 2D reference electrodes). In addition, small prototype pouch cells are investigated and the thickness change during (dis)charging is less than one third compared to a bare lithium metal electrode. This demonstrates low breathing behavior of the CVD-YP electrode and confirms the reversible storage of metallic lithium within the 3D carbon-based composite electrode.