The importance of crystal size for breathing kinetics in MIL-53(Al)
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
Herein we analyze the switching kinetics of a breathing framework MIL-53(Al) with respect to different crystallite size regimes. Synchrotron time-resolved powder X-ray diffraction (PXRD) and adsorption rate analysis of n-butane physisorption at 298 K demonstrate the decisive role of crystal size affecting the time domain of breathing transitions in MIL-53(Al).
Details
| Original language | English |
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| Pages (from-to) | 10492-10495 |
| Number of pages | 4 |
| Journal | Chemical communications |
| Volume | 58 |
| Issue number | 75 |
| Publication status | Published - 22 Aug 2022 |
| Peer-reviewed | Yes |
External IDs
| PubMed | 36043355 |
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